Efficient C–H bond activations via O(2) cleavage by a dianionic cobalt(ii) complex

A dianionic, square planar cobalt(ii) complex reacts with O(2) in the presence of acetonitrile to give a cyanomethylcobalt(iii) complex formed by C–H bond cleavage. Interestingly, PhIO and p-tolyl azide react similarly to give the same cyanomethylcobalt(iii) complex. Competition studies with various...

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Detalles Bibliográficos
Autores principales: Nguyen, Andy I., Hadt, Ryan G., Solomon, Edward I., Tilley, T. Don
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2014
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4111274/
https://www.ncbi.nlm.nih.gov/pubmed/25071930
http://dx.doi.org/10.1039/c4sc00108g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4111274/
https://www.ncbi.nlm.nih.gov/pubmed/25071930
http://dx.doi.org/10.1039/c4sc00108g

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