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Chain-End-Functionalized Polyphosphazenes via a One-Pot Phosphine-Mediated Living Polymerization
A simple polymerization of trichlorophosphoranimine (Cl(3)P = N−SiMe(3)) mediated by functionalized triphenylphosphines is presented. In situ initiator formation and the subsequent polymerization progress are investigated by (31)P NMR spectroscopy, demonstrating a living cationic polymerization mech...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
BlackWell Publishing Ltd
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4115175/ https://www.ncbi.nlm.nih.gov/pubmed/24700544 http://dx.doi.org/10.1002/marc.201400114 |