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Terminal Olefins to Chromans, Isochromans, and Pyrans via Allylic C–H Oxidation

[Image: see text] The synthesis of chroman, isochroman, and pyran motifs has been accomplished via a combination of Pd(II)/bis-sulfoxide C–H activation and Lewis acid co-catalysis. A wide range of alcohols are found to be competent nucleophiles for the transformation under uniform conditions (cataly...

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Detalles Bibliográficos
Autores principales: Ammann, Stephen E., Rice, Grant T., White, M. Christina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4132955/
https://www.ncbi.nlm.nih.gov/pubmed/24983326
http://dx.doi.org/10.1021/ja503322e