Molybdenum Catalyzed Ammonia Borane Dehydrogenation: Oxidation State Specific Mechanisms

[Image: see text] Though numerous catalysts for the dehydrogenation of ammonia borane (AB) are known, those that release >2 equiv of H(2) are uncommon. Herein, we report the synthesis of Mo complexes supported by a para-terphenyl diphosphine ligand, 1, displaying metal–arene interactions. Both a...

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Detalles Bibliográficos
Autores principales: Buss, Joshua A., Edouard, Guy A., Cheng, Christine, Shi, Jade, Agapie, Theodor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4140452/
https://www.ncbi.nlm.nih.gov/pubmed/25034459
http://dx.doi.org/10.1021/ja5059923

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4140452/
https://www.ncbi.nlm.nih.gov/pubmed/25034459
http://dx.doi.org/10.1021/ja5059923

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