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Molybdenum Catalyzed Ammonia Borane Dehydrogenation: Oxidation State Specific Mechanisms
[Image: see text] Though numerous catalysts for the dehydrogenation of ammonia borane (AB) are known, those that release >2 equiv of H(2) are uncommon. Herein, we report the synthesis of Mo complexes supported by a para-terphenyl diphosphine ligand, 1, displaying metal–arene interactions. Both a...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4140452/ https://www.ncbi.nlm.nih.gov/pubmed/25034459 http://dx.doi.org/10.1021/ja5059923 |