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Photoredox α-Vinylation of α-Amino Acids and N-Aryl Amines

[Image: see text] A new coupling protocol has been developed that allows the union of vinyl sulfones with photoredox-generated α-amino radicals to provide allylic amines of broad diversity. Direct C–H vinylations of N-aryl tertiary amines, as well as decarboxylative vinylations of N-Boc α-amino acid...

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Detalles Bibliográficos
Autores principales: Noble, Adam, MacMillan, David W. C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4140496/
https://www.ncbi.nlm.nih.gov/pubmed/25026314
http://dx.doi.org/10.1021/ja506094d