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Identification of the Valence and Coordination Environment of the Particulate Methane Monooxygenase Copper Centers by Advanced EPR Characterization

[Image: see text] Particulate methane monooxygenase (pMMO) catalyzes the oxidation of methane to methanol in methanotrophic bacteria. As a copper-containing enzyme, pMMO has been investigated extensively by electron paramagnetic resonance (EPR) spectroscopy, but the presence of multiple copper cente...

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Detalles Bibliográficos
Autores principales: Culpepper, Megen A., Cutsail III, George E., Gunderson, William A., Hoffman, Brian M., Rosenzweig, Amy C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4140498/
https://www.ncbi.nlm.nih.gov/pubmed/25059917
http://dx.doi.org/10.1021/ja5053126