Diastereo- and Enantioselective Reactions of Bis(pinacolato)diboron, 1,3-Enynes, and Aldehydes Catalyzed by an Easily Accessible Bisphosphine–Cu Complex

[Image: see text] Catalytic enantioselective multicomponent processes involving bis(pinacolato)diboron [B(2)(pin)(2)], 1,3-enynes, and aldehydes are disclosed; the resulting compounds contain a primary C–B(pin) bond, as well as alkyne- and hydroxyl-substituted tertiary carbon stereogenic centers. A...

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Detalles Bibliográficos
Autores principales: Meng, Fanke, Haeffner, Fredrik, Hoveyda, Amir H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4140502/
https://www.ncbi.nlm.nih.gov/pubmed/25089917
http://dx.doi.org/10.1021/ja5071202

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4140502/
https://www.ncbi.nlm.nih.gov/pubmed/25089917
http://dx.doi.org/10.1021/ja5071202

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