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Vibrational Anharmonicities and Reactivity of Tetrafluoroethylene

[Image: see text] Compared to ethylene and its nonfluorinated derivatives, C(2)F(4) is peculiar in many reactions. It very easily adds to radicals and prefers formation of four-membered rings over Diels–Alder reactions. This has been rationalized by the preference of fluorine for carbon sp(3) hybrid...

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Detalles Bibliográficos
Autores principales: Fuß, Werner, Robertson, Evan G., Medcraft, Chris, Appadoo, Dominique R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4141698/
https://www.ncbi.nlm.nih.gov/pubmed/24896662
http://dx.doi.org/10.1021/jp500811w