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Vibrational Anharmonicities and Reactivity of Tetrafluoroethylene
[Image: see text] Compared to ethylene and its nonfluorinated derivatives, C(2)F(4) is peculiar in many reactions. It very easily adds to radicals and prefers formation of four-membered rings over Diels–Alder reactions. This has been rationalized by the preference of fluorine for carbon sp(3) hybrid...
Autores principales: | Fuß, Werner, Robertson, Evan G., Medcraft, Chris, Appadoo, Dominique R. T. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2014
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4141698/ https://www.ncbi.nlm.nih.gov/pubmed/24896662 http://dx.doi.org/10.1021/jp500811w |
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