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Improving the reactivity of phenylacetylene macrocycles toward topochemical polymerization by side chains modification

The synthesis and self-assembly of two new phenylacetylene macrocycle (PAM) organogelators were performed. Polar 2-hydroxyethoxy side chains were incorporated in the inner part of the macrocycles to modify the assembly mode in the gel state. With this modification, it was possible to increase the re...

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Detalles Bibliográficos
Autores principales: Rondeau-Gagné, Simon, Néabo, Jules Roméo, Daigle, Maxime, Cantin, Katy, Morin, Jean-François
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4142893/
https://www.ncbi.nlm.nih.gov/pubmed/25161718
http://dx.doi.org/10.3762/bjoc.10.167