Electron Paramagnetic Resonance and Electron-Nuclear Double Resonance Studies of the Reactions of Cryogenerated Hydroperoxoferric–Hemoprotein Intermediates

[Image: see text] The fleeting ferric peroxo and hydroperoxo intermediates of dioxygen activation by hemoproteins can be readily trapped and characterized during cryoradiolytic reduction of ferrous hemoprotein–O(2) complexes at 77 K. Previous cryoannealing studies suggested that the relaxation of cr...

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Detalles Bibliográficos
Autores principales: Davydov, Roman, Laryukhin, Mikhail, Ledbetter-Rogers, Amy, Sono, Masanori, Dawson, John H., Hoffman, Brian M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4144713/
https://www.ncbi.nlm.nih.gov/pubmed/25046203
http://dx.doi.org/10.1021/bi500296d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4144713/
https://www.ncbi.nlm.nih.gov/pubmed/25046203
http://dx.doi.org/10.1021/bi500296d

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