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Cooperative activation of cyclobutanones and olefins leads to bridged-ring systems by a catalytic [4+2] coupling

Bridged-ring systems are widely found in natural products and successful syntheses of them frequently feature intramolecular Diels-Alder (IMDA) reactions. These reactions are subclassified as either type I or type II IMDAs depending on how the diene motif is tethered to the rest of the substrate - t...

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Detalles Bibliográficos
Autores principales: Ko, Haye Min, Dong, Guangbin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4150356/
https://www.ncbi.nlm.nih.gov/pubmed/25054946
http://dx.doi.org/10.1038/nchem.1989