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Systematic Tuning of Heme Redox Potentials and Its Effects on O(2) Reduction Rates in a Designed Oxidase in Myoglobin
[Image: see text] Cytochrome c Oxidase (CcO) is known to catalyze the reduction of O(2) to H(2)O efficiently with a much lower overpotential than most other O(2) reduction catalysts. However, methods by which the enzyme fine-tunes the reduction potential (E°) of its active site and the corresponding...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4151708/ https://www.ncbi.nlm.nih.gov/pubmed/25076049 http://dx.doi.org/10.1021/ja5054863 |