Alkynes as Allylmetal Equivalents in Redox-Triggered C–C Couplings to Primary Alcohols: (Z)-Homoallylic Alcohols via Ruthenium-Catalyzed Propargyl C–H Oxidative Addition

[Image: see text] The cationic ruthenium catalyst generated upon the acid–base reaction of H(2)Ru(CO)(PPh(3))(3) and 2,4,6-(2-Pr)(3)PhSO(3)H promotes the redox-triggered C–C coupling of 2-alkynes and primary alcohols to form (Z)-homoallylic alcohols with good to complete control of olefin geometry....

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Detalles Bibliográficos
Autores principales: Park, Boyoung Y., Nguyen, Khoa D., Chaulagain, Mani Raj, Komanduri, Venukrishnan, Krische, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4151781/
https://www.ncbi.nlm.nih.gov/pubmed/25075434
http://dx.doi.org/10.1021/ja505962w

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4151781/
https://www.ncbi.nlm.nih.gov/pubmed/25075434
http://dx.doi.org/10.1021/ja505962w

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