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Rates of Hexadehydro-Diels–Alder (HDDA) Cyclizations: Impact of the Linker Structure
[Image: see text] The rates of the hexadehydro-Diels–Alder (HDDA) reaction of substrates containing, minimally, a 1,3,8-triyne subunit are reported. Several series of related substrates, differing in the nature of the three-atom tether that links the 1,3-diyne and diynophile, were examined. Seemingl...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4156263/ https://www.ncbi.nlm.nih.gov/pubmed/25153729 http://dx.doi.org/10.1021/ol502131r |