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Unraveling the Interplay of Backbone Rigidity and Electron Rich Side-Chains on Electron Transfer in Peptides: The Realization of Tunable Molecular Wires

[Image: see text] Electrochemical studies are reported on a series of peptides constrained into either a 3(10)-helix (1–6) or β-strand (7–9) conformation, with variable numbers of electron rich alkene containing side chains. Peptides (1 and 2) and (7 and 8) are further constrained into these geometr...

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Detalles Bibliográficos
Autores principales: Horsley, John R., Yu, Jingxian, Moore, Katherine E., Shapter, Joe G., Abell, Andrew D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4156867/
https://www.ncbi.nlm.nih.gov/pubmed/25122122
http://dx.doi.org/10.1021/ja507175b