Protonation of Nickel–Iron Hydrogenase Models Proceeds after Isomerization at Nickel

[Image: see text] Theory and experiment indicate that the protonation of reduced NiFe dithiolates proceeds via a previously undetected isomer with enhanced basicity. In particular, it is proposed that protonation of (OC)(3)Fe(pdt)Ni(dppe) (1; pdt(2–) = (–)S(CH(2))(3)S(–); dppe = Ph(2)P(CH(2))(2)PPh(...

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Detalles Bibliográficos
Autores principales: Huynh, Mioy T., Schilter, David, Hammes-Schiffer, Sharon, Rauchfuss, Thomas B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4156870/
https://www.ncbi.nlm.nih.gov/pubmed/25094041
http://dx.doi.org/10.1021/ja505783z

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4156870/
https://www.ncbi.nlm.nih.gov/pubmed/25094041
http://dx.doi.org/10.1021/ja505783z

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