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Protonation of Nickel–Iron Hydrogenase Models Proceeds after Isomerization at Nickel
[Image: see text] Theory and experiment indicate that the protonation of reduced NiFe dithiolates proceeds via a previously undetected isomer with enhanced basicity. In particular, it is proposed that protonation of (OC)(3)Fe(pdt)Ni(dppe) (1; pdt(2–) = (–)S(CH(2))(3)S(–); dppe = Ph(2)P(CH(2))(2)PPh(...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4156870/ https://www.ncbi.nlm.nih.gov/pubmed/25094041 http://dx.doi.org/10.1021/ja505783z |