Nitrite and Hydroxylamine as Nitrogenase Substrates: Mechanistic Implications for the Pathway of N(2) Reduction

[Image: see text] Investigations of reduction of nitrite (NO(2)(–)) to ammonia (NH(3)) by nitrogenase indicate a limiting stoichiometry, NO(2)(–) + 6e(–) + 12ATP + 7H(+) → NH(3) + 2H(2)O + 12ADP + 12P(i). Two intermediates freeze-trapped during NO(2)(–) turnover by nitrogenase variants and investiga...

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Detalles Bibliográficos
Autores principales: Shaw, Sudipta, Lukoyanov, Dmitriy, Danyal, Karamatullah, Dean, Dennis R., Hoffman, Brian M., Seefeldt, Lance C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4160268/
https://www.ncbi.nlm.nih.gov/pubmed/25136926
http://dx.doi.org/10.1021/ja507123d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4160268/
https://www.ncbi.nlm.nih.gov/pubmed/25136926
http://dx.doi.org/10.1021/ja507123d

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