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From Racemic Alcohols to Enantiopure Amines: Ru-Catalyzed Diastereoselective Amination
[Image: see text] A commercially available ruthenium(II) PNP-type pincer catalyst (Ru-Macho) promotes the formation of α-chiral tert-butanesulfinylamines from racemic secondary alcohols and Ellman’s chiral tert-butanesulfinamide via a hydrogen borrowing strategy. The formation of α-chiral tert-butan...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4160272/ https://www.ncbi.nlm.nih.gov/pubmed/25170560 http://dx.doi.org/10.1021/ja5058482 |