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From Racemic Alcohols to Enantiopure Amines: Ru-Catalyzed Diastereoselective Amination

[Image: see text] A commercially available ruthenium(II) PNP-type pincer catalyst (Ru-Macho) promotes the formation of α-chiral tert-butanesulfinylamines from racemic secondary alcohols and Ellman’s chiral tert-butanesulfinamide via a hydrogen borrowing strategy. The formation of α-chiral tert-butan...

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Detalles Bibliográficos
Autores principales:	Oldenhuis, Nathan J., Dong, Vy M., Guan, Zhibin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4160272/ https://www.ncbi.nlm.nih.gov/pubmed/25170560 http://dx.doi.org/10.1021/ja5058482

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