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Copper–Peptide Complex Structure and Reactivity When Found in Conserved His-X(aa)-His Sequences

[Image: see text] Oxygen-activating copper proteins may possess His-X(aa)-His chelating sequences at their active sites and additionally exhibit imidiazole group δN vs εN tautomeric preferences. As shown here, such variations strongly affect copper ion’s coordination geometry, redox behavior, and ox...

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Detalles Bibliográficos
Autores principales: Park, Ga Young, Lee, Jung Yoon, Himes, Richard A., Thomas, Gnana S., Blackburn, Ninian J., Karlin, Kenneth D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4160276/
https://www.ncbi.nlm.nih.gov/pubmed/25171435
http://dx.doi.org/10.1021/ja505098v