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The Influence of Oxygen on [NiFe]–Hydrogenase Cofactor Biosynthesis and How Ligation of Carbon Monoxide Precedes Cyanation

The class of [NiFe]–hydrogenases is characterized by a bimetallic cofactor comprising low–spin nickel and iron ions, the latter of which is modified with a single carbon monoxide (CO) and two cyanide (CN(−)) molecules. Generation of these ligands in vivo requires a complex maturation apparatus in wh...

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Detalles Bibliográficos
Autores principales: Stripp, Sven T., Lindenstrauss, Ute, Granich, Claudia, Sawers, R. Gary, Soboh, Basem
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Public Library of Science 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4161419/
https://www.ncbi.nlm.nih.gov/pubmed/25211029
http://dx.doi.org/10.1371/journal.pone.0107488