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Intriguing mechanistic labyrinths in gold(i) catalysis

Many mechanistically intriguing reactions have been developed in the last decade using gold(i) as catalyst. Here we review the main mechanistic proposals in gold-catalysed activation of alkynes and allenes, in which this metal plays a central role by stabilising a variety of complex cationic interme...

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Detalles Bibliográficos
Autores principales: Obradors, Carla, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4162457/
https://www.ncbi.nlm.nih.gov/pubmed/24176910
http://dx.doi.org/10.1039/c3cc45518a