Intriguing mechanistic labyrinths in gold(i) catalysis

Many mechanistically intriguing reactions have been developed in the last decade using gold(i) as catalyst. Here we review the main mechanistic proposals in gold-catalysed activation of alkynes and allenes, in which this metal plays a central role by stabilising a variety of complex cationic interme...

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Detalles Bibliográficos
Autores principales: Obradors, Carla, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2014
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4162457/
https://www.ncbi.nlm.nih.gov/pubmed/24176910
http://dx.doi.org/10.1039/c3cc45518a
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author Obradors, Carla
Echavarren, Antonio M.
author_facet Obradors, Carla
Echavarren, Antonio M.
author_sort Obradors, Carla
collection PubMed
description Many mechanistically intriguing reactions have been developed in the last decade using gold(i) as catalyst. Here we review the main mechanistic proposals in gold-catalysed activation of alkynes and allenes, in which this metal plays a central role by stabilising a variety of complex cationic intermediates.
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spelling pubmed-41624572014-09-24 Intriguing mechanistic labyrinths in gold(i) catalysis Obradors, Carla Echavarren, Antonio M. Chem Commun (Camb) Chemistry Many mechanistically intriguing reactions have been developed in the last decade using gold(i) as catalyst. Here we review the main mechanistic proposals in gold-catalysed activation of alkynes and allenes, in which this metal plays a central role by stabilising a variety of complex cationic intermediates. Royal Society of Chemistry 2014-01-04 2013-10-31 /pmc/articles/PMC4162457/ /pubmed/24176910 http://dx.doi.org/10.1039/c3cc45518a Text en This journal is © The Royal Society of Chemistry 2013 https://creativecommons.org/licenses/by-nc/3.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution-NonCommercial 3.0 Unported License (http://creativecommons.org/licenses/by-nc/3.0/ (https://creativecommons.org/licenses/by-nc/3.0/) ) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Obradors, Carla
Echavarren, Antonio M.
Intriguing mechanistic labyrinths in gold(i) catalysis
title Intriguing mechanistic labyrinths in gold(i) catalysis
title_full Intriguing mechanistic labyrinths in gold(i) catalysis
title_fullStr Intriguing mechanistic labyrinths in gold(i) catalysis
title_full_unstemmed Intriguing mechanistic labyrinths in gold(i) catalysis
title_short Intriguing mechanistic labyrinths in gold(i) catalysis
title_sort intriguing mechanistic labyrinths in gold(i) catalysis
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4162457/
https://www.ncbi.nlm.nih.gov/pubmed/24176910
http://dx.doi.org/10.1039/c3cc45518a
work_keys_str_mv AT obradorscarla intriguingmechanisticlabyrinthsingoldicatalysis
AT echavarrenantoniom intriguingmechanisticlabyrinthsingoldicatalysis

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