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Exciplexes versus Loose Ion Pairs: How Does the Driving Force Impact the Initial Product Ratio of Photoinduced Charge Separation Reactions?

[Image: see text] Many donor–acceptor systems can undergo a photoinduced charge separation reaction, yielding loose ion pairs (LIPs). LIPs can be formed either directly via (distant) electron transfer (ET) or indirectly via the dissociation of an initially formed exciplex or tight ion pair. Establis...

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Detalles Bibliográficos
Autores principales: Hoang, Hao Minh, Pham, Thi Bich Van, Grampp, Günter, Kattnig, Daniel R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4166680/
https://www.ncbi.nlm.nih.gov/pubmed/25243054
http://dx.doi.org/10.1021/jz501575r