Cargando…

Building complex carbon skeletons with ethynyl[2.2]paracyclophanes

Ethynyl[2.2]paracyclophanes are shown to be useful substrates for the preparation of complex, highly unsaturated carbon frameworks. Thus both the pseudo-geminal- 2 and the pseudo-ortho-diethynylcyclophane 4 can be dimerized by Glaser coupling to the respective dimers 9/10 and 11/12. Whereas the form...

Descripción completa

Detalles Bibliográficos
Autores principales: Dix, Ina, Bondarenko, Lidija, Jones, Peter G, Oeser, Thomas, Hopf, Henning
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4168697/
https://www.ncbi.nlm.nih.gov/pubmed/25246960
http://dx.doi.org/10.3762/bjoc.10.209