Photorelease of phosphates: Mild methods for protecting phosphate derivatives

We have developed a new photoremovable protecting group for caging phosphates in the near UV. Diethyl 2-(4-hydroxy-1-naphthyl)-2-oxoethyl phosphate (14a) quantitatively releases diethyl phosphate upon irradiation in aq MeOH or aq MeCN at 350 nm, with quantum efficiencies ranging from 0.021 to 0.067...

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Detalles Bibliográficos
Autores principales: Senadheera, Sanjeewa N, Yousef, Abraham L, Givens, Richard S
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4168878/
https://www.ncbi.nlm.nih.gov/pubmed/25246963
http://dx.doi.org/10.3762/bjoc.10.212

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4168878/
https://www.ncbi.nlm.nih.gov/pubmed/25246963
http://dx.doi.org/10.3762/bjoc.10.212

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