Relay cross metathesis reactions of vinylphosphonates

Dimethyl (β-substituted) vinylphosphonates do not readily undergo cross metathesis reactions with Grubbs catalyst and terminal alkenes. However, the corresponding mono- or diallyl vinylphosphonate esters undergo facile cross metathesis reactions. The improved reactivity is attributed to a relay step...

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Detalles Bibliográficos
Autores principales: Malla, Raj K, Ridenour, Jeremy N, Spilling, Christopher D
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4168886/
https://www.ncbi.nlm.nih.gov/pubmed/25246952
http://dx.doi.org/10.3762/bjoc.10.201

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4168886/
https://www.ncbi.nlm.nih.gov/pubmed/25246952
http://dx.doi.org/10.3762/bjoc.10.201

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