Cargando…
Relay cross metathesis reactions of vinylphosphonates
Dimethyl (β-substituted) vinylphosphonates do not readily undergo cross metathesis reactions with Grubbs catalyst and terminal alkenes. However, the corresponding mono- or diallyl vinylphosphonate esters undergo facile cross metathesis reactions. The improved reactivity is attributed to a relay step...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2014
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4168886/ https://www.ncbi.nlm.nih.gov/pubmed/25246952 http://dx.doi.org/10.3762/bjoc.10.201 |
| _version_ | 1782335637658009600 |
|---|---|
| author | Malla, Raj K Ridenour, Jeremy N Spilling, Christopher D |
| author_facet | Malla, Raj K Ridenour, Jeremy N Spilling, Christopher D |
| author_sort | Malla, Raj K |
| collection | PubMed |
| description | Dimethyl (β-substituted) vinylphosphonates do not readily undergo cross metathesis reactions with Grubbs catalyst and terminal alkenes. However, the corresponding mono- or diallyl vinylphosphonate esters undergo facile cross metathesis reactions. The improved reactivity is attributed to a relay step in the cross metathesis reaction mechanism. |
| format | Online Article Text |
| id | pubmed-4168886 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | Beilstein-Institut |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-41688862014-09-22 Relay cross metathesis reactions of vinylphosphonates Malla, Raj K Ridenour, Jeremy N Spilling, Christopher D Beilstein J Org Chem Full Research Paper Dimethyl (β-substituted) vinylphosphonates do not readily undergo cross metathesis reactions with Grubbs catalyst and terminal alkenes. However, the corresponding mono- or diallyl vinylphosphonate esters undergo facile cross metathesis reactions. The improved reactivity is attributed to a relay step in the cross metathesis reaction mechanism. Beilstein-Institut 2014-08-19 /pmc/articles/PMC4168886/ /pubmed/25246952 http://dx.doi.org/10.3762/bjoc.10.201 Text en Copyright © 2014, Malla et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
| spellingShingle | Full Research Paper Malla, Raj K Ridenour, Jeremy N Spilling, Christopher D Relay cross metathesis reactions of vinylphosphonates |
| title | Relay cross metathesis reactions of vinylphosphonates |
| title_full | Relay cross metathesis reactions of vinylphosphonates |
| title_fullStr | Relay cross metathesis reactions of vinylphosphonates |
| title_full_unstemmed | Relay cross metathesis reactions of vinylphosphonates |
| title_short | Relay cross metathesis reactions of vinylphosphonates |
| title_sort | relay cross metathesis reactions of vinylphosphonates |
| topic | Full Research Paper |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4168886/ https://www.ncbi.nlm.nih.gov/pubmed/25246952 http://dx.doi.org/10.3762/bjoc.10.201 |
| work_keys_str_mv | AT mallarajk relaycrossmetathesisreactionsofvinylphosphonates AT ridenourjeremyn relaycrossmetathesisreactionsofvinylphosphonates AT spillingchristopherd relaycrossmetathesisreactionsofvinylphosphonates |