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P(O)R(2)-directed Pd-catalyzed C–H functionalization of biaryl derivatives to synthesize chiral phosphorous ligands

Chiral phosphorus ligands have been widely used in transition metal-catalyzed asymmetric reactions. Herein, we report a new synthesis approach of chiral biaryls containing a phosphorus moiety using P(O)R(2)-directed Pd-catalyzed C–H activation; the functionalized products are produced with good enan...

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Detalles Bibliográficos
Autores principales: Hu, Rong-Bin, Wang, Hong-Li, Zhang, Hong-Yu, Zhang, Heng, Ma, Yan-Na, Yang, Shang-dong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4168959/
https://www.ncbi.nlm.nih.gov/pubmed/25246966
http://dx.doi.org/10.3762/bjoc.10.215