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P(O)R(2)-directed Pd-catalyzed C–H functionalization of biaryl derivatives to synthesize chiral phosphorous ligands
Chiral phosphorus ligands have been widely used in transition metal-catalyzed asymmetric reactions. Herein, we report a new synthesis approach of chiral biaryls containing a phosphorus moiety using P(O)R(2)-directed Pd-catalyzed C–H activation; the functionalized products are produced with good enan...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4168959/ https://www.ncbi.nlm.nih.gov/pubmed/25246966 http://dx.doi.org/10.3762/bjoc.10.215 |