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Local Isotropic Diffusion Approximation for Coupled Internal and Overall Molecular Motions in NMR Spin Relaxation

[Image: see text] The present work demonstrates that NMR spin relaxation rate constants for molecules interconverting between states with different diffusion tensors can be modeled theoretically by combining orientational correlation functions for exchanging spherical molecules with locally isotropi...

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Detalles Bibliográficos
Autores principales: Gill, Michelle L., Palmer, Arthur G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4174990/
https://www.ncbi.nlm.nih.gov/pubmed/25167331
http://dx.doi.org/10.1021/jp506580c