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Symmetry-Breaking Charge Transfer of Visible Light Absorbing Systems: Zinc Dipyrrins

[Image: see text] Zinc dipyrrin complexes with two identical dipyrrin ligands absorb strongly at 450–550 nm and exhibit high fluorescence quantum yields in nonpolar solvents (e.g., 0.16–0.66 in cyclohexane) and weak to nonexistent emission in polar solvents (i.e., <10(–3), in acetonitrile). The l...

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Detalles Bibliográficos
Autores principales: Trinh, Cong, Kirlikovali, Kent, Das, Saptaparna, Ener, Maraia E., Gray, Harry B., Djurovich, Peter, Bradforth, Stephen E., Thompson, Mark E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4174994/
https://www.ncbi.nlm.nih.gov/pubmed/25270268
http://dx.doi.org/10.1021/jp506855t