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The Semiquinone at the Q(i) Site of the bc(1) Complex Explored Using HYSCORE Spectroscopy and Specific Isotopic Labeling of Ubiquinone in Rhodobacter sphaeroides via (13)C Methionine and Construction of a Methionine Auxotroph

[Image: see text] Specific isotopic labeling at the residue or substituent level extends the scope of different spectroscopic approaches to the atomistic level. Here we describe (13)C isotopic labeling of the methyl and methoxy ring substituents of ubiquinone, achieved through construction of a meth...

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Detalles Bibliográficos
Autores principales: Hong, Sangjin, de Almeida, Wagner B., Taguchi, Alexander T., Samoilova, Rimma I., Gennis, Robert B., O’Malley, Patrick J., Dikanov, Sergei A., Crofts, Antony R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4179594/
https://www.ncbi.nlm.nih.gov/pubmed/25184535
http://dx.doi.org/10.1021/bi500654y