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Catalytic, Enantioselective Sulfenylation of Ketone-Derived Enoxysilanes
[Image: see text] A catalytic, enantioselective, Lewis base-catalyzed α-sulfenylation of silyl enol ethers has been developed. To avoid acidic hydrolysis of the silyl enol ether substrates, a sulfenylating agent that did not require additional Brønsted acid activation, namely N-phenylthiosaccharin,...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4183607/ https://www.ncbi.nlm.nih.gov/pubmed/25192220 http://dx.doi.org/10.1021/ja506133z |