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Structurally Similar Triphenylphosphine-Stabilized Undecagolds, Au(11)(PPh(3))(7)Cl(3) and [Au(11)(PPh(3))(8)Cl(2)]Cl, Exhibit Distinct Ligand Exchange Pathways with Glutathione

[Image: see text] Ligand exchange is frequently used to introduce new functional groups on the surface of inorganic nanoparticles or clusters while preserving the core size. For one of the smallest clusters, triphenylphosphine (TPP)-stabilized undecagold, there are conflicting reports in the literat...

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Detalles Bibliográficos
Autores principales: McKenzie, Lallie C., Zaikova, Tatiana O., Hutchison, James E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4183609/
https://www.ncbi.nlm.nih.gov/pubmed/25171178
http://dx.doi.org/10.1021/ja5075689