Direct Observation of a Nonheme Iron(IV)–Oxo Complex That Mediates Aromatic C–F Hydroxylation

[Image: see text] The synthesis of a pentadentate ligand with strategically designed fluorinated arene groups in the second coordination sphere of a nonheme iron center is reported. The oxidatively resistant fluorine substituents allow for the trapping and characterization of an Fe(IV)(O) complex at...

Descripción completa

Detalles Bibliográficos
Autores principales: Sahu, Sumit, Quesne, Matthew G., Davies, Casey G., Dürr, Maximilian, Ivanović-Burmazović, Ivana, Siegler, Maxime A., Jameson, Guy N. L., de Visser, Sam P., Goldberg, David P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4183621/
https://www.ncbi.nlm.nih.gov/pubmed/25246108
http://dx.doi.org/10.1021/ja507346t

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4183621/
https://www.ncbi.nlm.nih.gov/pubmed/25246108
http://dx.doi.org/10.1021/ja507346t

Ejemplares similares