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A 10(6)-Fold Enhancement in N(2)-Binding Affinity of an Fe(2)(μ-H)(2) Core upon Reduction to a Mixed-Valence Fe(II)Fe(I) State
[Image: see text] Transient hydride ligands bridging two or more iron centers purportedly accumulate on the iron–molybdenum cofactor (FeMoco) of nitrogenase, and their role in the reduction of N(2) to NH(3) is unknown. One role of these ligands may be to facilitate N(2) coordination at an iron site...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4183624/ https://www.ncbi.nlm.nih.gov/pubmed/25184795 http://dx.doi.org/10.1021/ja507217v |