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Reversible H Atom Abstraction Catalyzed by the Radical S-Adenosylmethionine Enzyme HydG
[Image: see text] The organometallic H-cluster at the active site of [FeFe]-hydrogenases is synthesized by three accessory proteins, two of which are radical S-adenosylmethionine enzymes (HydE, HydG) and one of which is a GTPase (HydF). In this work we probed the specific role of H atom abstraction...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4183638/ https://www.ncbi.nlm.nih.gov/pubmed/25099480 http://dx.doi.org/10.1021/ja504618y |