Mechanism of the Reactions of Alcohols with o-Benzynes

[Image: see text] We have studied reactions of secondary and primary alcohols with benzynes generated by the hexadehydro-Diels–Alder (HDDA) reaction. These alcohols undergo competitive addition vs dihydrogen transfer to produce aryl ethers vs reduced benzenoid products, respectively. During the latt...

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Detalles Bibliográficos
Autores principales: Willoughby, Patrick H., Niu, Dawen, Wang, Tao, Haj, Moriana K., Cramer, Christopher J., Hoye, Thomas R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4183651/
https://www.ncbi.nlm.nih.gov/pubmed/25232890
http://dx.doi.org/10.1021/ja502595m

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4183651/
https://www.ncbi.nlm.nih.gov/pubmed/25232890
http://dx.doi.org/10.1021/ja502595m

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