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The Taumycin A Macrocycle: Asymmetric Total Synthesis and Revision of Relative Stereochemistry
[Image: see text] The first asymmetric total synthesis and revision of the relative configuration of the 12-membered taumycin A macrocycle is described. Key to the success of this work was a novel α-keto ketene macrocyclization that provided an efficient means by which to access two diastereomers of...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4184443/ https://www.ncbi.nlm.nih.gov/pubmed/25248034 http://dx.doi.org/10.1021/ol5025585 |