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The Taumycin A Macrocycle: Asymmetric Total Synthesis and Revision of Relative Stereochemistry

[Image: see text] The first asymmetric total synthesis and revision of the relative configuration of the 12-membered taumycin A macrocycle is described. Key to the success of this work was a novel α-keto ketene macrocyclization that provided an efficient means by which to access two diastereomers of...

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Detalles Bibliográficos
Autores principales:	deGruyter, Justine N., Maio, William A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4184443/ https://www.ncbi.nlm.nih.gov/pubmed/25248034 http://dx.doi.org/10.1021/ol5025585

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