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Annulation Reactions of Allenyl Esters: An Approach to Bicyclic Diones and Medium-Sized Rings

[Image: see text] A flexible approach to construct sterically congested bicyclo-alkenedione frameworks is reported. Under the action of potassium carbonate, α-sulphonyl cycloalkanones are added to functionalized allenyl esters, leading to a lactone intermediate that is subsequently reduced to initia...

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Detalles Bibliográficos
Autores principales: Bhat, Bilal A., Maki, Samantha L., St.Germain, Elijah J., Maity, Pradip, Lepore, Salvatore D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4184455/
https://www.ncbi.nlm.nih.gov/pubmed/25184784
http://dx.doi.org/10.1021/jo501700c