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Crystal structure of tetra­guanidinium [hexa­hydrogen hexa­arsenato(V)tetra­vanadate(V)] tetra­hydrate

The complete polyoxidometallate anion in the title compound, (CH(6)N(3))(4)[H(6)V(4)As(6)O(30)]·4H(2)O, is generated by crystallographic inversion symmetry. The polyhedral building units are distorted VO(6) octa­hedra and AsO(3)OH tetra­hedra. The VO(6) units feature a short formal V=O double bond a...

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Detalles Bibliográficos
Autor principal: Harrison, William T. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186164/
https://www.ncbi.nlm.nih.gov/pubmed/25309172
http://dx.doi.org/10.1107/S1600536814011349