Impact of Substituents and Nonplanarity on Nickel and Copper Porphyrin Electrochemistry: First Observation of a Cu(II)/Cu(III) Reaction in Nonaqueous Media

[Image: see text] Electrochemical studies of the oxidation of dodecasubstituted and highly nonplanar nickel porphyrins in a noncoordinating solvent have previously revealed the first nickel(III) porphyrin dication. Herein, we investigate if these nonplanar porphyrins can also be used to detect the s...

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Detalles Bibliográficos
Autores principales: Fang, Yuanyuan, Senge, Mathias O., Van Caemelbecke, Eric, Smith, Kevin M., Medforth, Craig J., Zhang, Min, Kadish, Karl M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186666/
https://www.ncbi.nlm.nih.gov/pubmed/25253031
http://dx.doi.org/10.1021/ic502162p

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186666/
https://www.ncbi.nlm.nih.gov/pubmed/25253031
http://dx.doi.org/10.1021/ic502162p

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