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Spatial Control over Cross-Linking Dictates the pH-Responsive Behavior of Poly(2-(tert-butylamino)ethyl methacrylate) Brushes

[Image: see text] Surface-initiated atom transfer radical polymerization (ATRP) of 2-(tert-butylamino)ethyl methacrylate (TBAEMA) produced pH-responsive secondary amine-functionalized polymer brushes with dry thicknesses ranging from 4 to 28 nm, as determined by ellipsometry. At low pH, linear PTBAE...

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Detalles Bibliográficos
Autores principales: Alswieleh, Abdullah M., Cheng, Nan, Leggett, Graham J., Armes, Steven P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4190050/
https://www.ncbi.nlm.nih.gov/pubmed/24417283
http://dx.doi.org/10.1021/la403666y