Synthesis and vibrational spectroscopy of (57)Fe-labeled models of [NiFe] hydrogenase: first direct observation of a nickel–iron interaction

A new route to iron carbonyls has enabled synthesis of (57)Fe-labeled [NiFe] hydrogenase mimic (OC)(3) (57)Fe(pdt)Ni(dppe). Its study by nuclear resonance vibrational spectroscopy revealed Ni–(57)Fe vibrations, as confirmed by calculations. The modes are absent for [(OC)(3) (57)Fe(pdt)Ni(dppe)](+),...

Descripción completa

Detalles Bibliográficos
Autores principales: Schilter, David, Pelmenschikov, Vladimir, Wang, Hongxin, Meier, Florian, Gee, Leland B., Yoda, Yoshitaka, Kaupp, Martin, Rauchfuss, Thomas B., Cramer, Stephen P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2014
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4191989/
https://www.ncbi.nlm.nih.gov/pubmed/25237680
http://dx.doi.org/10.1039/c4cc04572f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4191989/
https://www.ncbi.nlm.nih.gov/pubmed/25237680
http://dx.doi.org/10.1039/c4cc04572f

Ejemplares similares