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Synthesis and vibrational spectroscopy of (57)Fe-labeled models of [NiFe] hydrogenase: first direct observation of a nickel–iron interaction

A new route to iron carbonyls has enabled synthesis of (57)Fe-labeled [NiFe] hydrogenase mimic (OC)(3) (57)Fe(pdt)Ni(dppe). Its study by nuclear resonance vibrational spectroscopy revealed Ni–(57)Fe vibrations, as confirmed by calculations. The modes are absent for [(OC)(3) (57)Fe(pdt)Ni(dppe)](+),...

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Detalles Bibliográficos
Autores principales:	Schilter, David, Pelmenschikov, Vladimir, Wang, Hongxin, Meier, Florian, Gee, Leland B., Yoda, Yoshitaka, Kaupp, Martin, Rauchfuss, Thomas B., Cramer, Stephen P.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2014
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4191989/ https://www.ncbi.nlm.nih.gov/pubmed/25237680 http://dx.doi.org/10.1039/c4cc04572f

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