Catalyst Control over Regio- and Enantioselectivity in Baeyer–Villiger Oxidations of Functionalized Ketones

[Image: see text] We report a peptide-based catalyst that can strongly influence the regio- and enantioselectivity of the Baeyer–Villiger (BV) oxidation of cyclic ketones bearing amide, urea, or sulfonamide functional groups. Both types of selectivity are thought to arise from a catalyst–substrate h...

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Detalles Bibliográficos
Autores principales: Romney, David K., Colvin, Sean M., Miller, Scott J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4195385/
https://www.ncbi.nlm.nih.gov/pubmed/25250713
http://dx.doi.org/10.1021/ja508757g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4195385/
https://www.ncbi.nlm.nih.gov/pubmed/25250713
http://dx.doi.org/10.1021/ja508757g

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